Assessment of geological source and geochemical dispersion of heavy metals in the sediments of brine springs in Khouzestan Province

Authors

1 Department of Geology, Faculty of Earth Sciences, Shahid Chamran University of Ahvaz, Ahvaz, Iran

2 Geological Survey of Iran, Southwestern Centre, Ahvaz, Iran

Abstract

The present work deals with the concentration and dispersion of heavy metals (i.e., Pb, Cd, Zn, Ni, Co, Cr, and As) in the sediment samples of 13 brine springs (i.e., Pirmusa, dual springs of Gare-Bardi, triple springs of Ghale-Madreseh, Batvand, Kuhzar, Aghili, Haftanan, Ghasem-Abad, Ispareh, and Dobalutan) in the Khouzestan Province. Geologically, these springs are located in the Zagros Fold and Thrust Belt (ZFTB) and emerged in the Gachsaran Formation. Besides characterizing the geological features, the dispersion of heavy metals were interpreted using geo-environmental parameters including contamination factor (Cf), enrichment factor (Ef), potential ecological risk (Eri), and modified ecological risk index (MRI) with statistical methods including Principal Components Analysis (PCA). Most of the studied samples represent Cf Cf <3, indicating low to moderate (for Cd, Pb, and As) degrees of contamination. Also, the majority of studied samples represent Ef >1 and Ef ≤ 3.53 which suggest minimum to moderate degrees of enrichment. Except for Cd contents in the Ghale-Madreseh 3 and Gare-Bardi 2 samples, the rest of other samples totally exhibit low levels of Eri. Also, the values of modified ecological risk index are categorized in low rick field. Principal component analysis (PCA) implies that Co contents were sourced from the Gachsaran lithology, while As, Ni, Cr, Pb, and Cd are most probably related to the contribution of oil-field related brines.

Keywords


Abrahim, G.M.S., Parker, R.J., 2008. Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental Monitoring and Assessment 136, 227-38.
Absalon, D., Slesak, B., 2010. The effects of changes in cadmium and lead air pollution on cancer incidence in children. Science of the Total Environment 408, 4420-4428.
Adibi, H., Mazhari, M., Bidoki, S. K., Mahmoodi, M., 2014. The effect of washing and soaking on decreasing heavy metals (Pb, Cd and As) in the rice distributed in Kermanshah in 2011. Journal of Kermanshah University of Medical Sciences 17, 628-636.
Al-Khashman, O.A., 2007. The investigation of metal concentrations in street dust samples in Aqaba city, Jordan. Environmental Geochemistry and Health 29, 197–207.
Bahroudi, A, Koyi, H.A., 2004. Tectono-sedimentary framework of the Gachsaran Formation in the Zagros foreland basin. Marine and Petroleum Geology 21, 1295–1310.
Brady, J.P., Ayoko, G.A., Martens, W.N., Goonetilleke, A., 2015. Development of a hybrid pollution index for heavy metals in marine and estuarine sediments. Environmental Monitoring and Assessment 187, 306.
 Duodu, G.O., Goonetilleke, A., Ayoko, G.A., 2016. Comparison of pollution indices for the assessment of heavy metal in Brisbane River sediment. Environmental Pollution 219, 1077–1091.
Gao, H., Bai, J., Xiao, R., Liu, P., Jiang, W., Wang, J., 2013. Levels, sources and risk assessment of trace elements in wetland soils of a typical shallow freshwater lake, China. Stochastic Environmental Research and Risk 27, 275–284.
Gonzalez, A., Rodriguez, M., Sanchez, J.C., Espinosa, A.J., La Rosa, F.J., 2000. Assessment of metals in sediments in a tributary of Guadalquivir River (Spain). Heavy metal partitioning and relation between the water and sediment system water. Air and soil pollution 121, 11-29.
Habibi, T., Ruban, D.A., 2017. Outstanding diversity of heritage features in large geological bodies: The Gachsaran Formation in southwest Iran. Journal of African Earth Sciences 133, 1-6.
Hair, J.F., Black, W.C., Babin, B.J., Anderson, R.E., 2009. Multivariate Data Analysis. Pearson Publication, 7th Edition, 816pp.
Hakanson, L., 1980. An ecological risk index for aquatic pollution control a sedimentological approach. Water Research 14, 975- 1001.
Hardi, M., Siregar, Y.I., Anita, S., Ilza, M., 2019. Determination of heavy metals concentration in produced water of oil field exploration in siak regency. Journal of Physics: Conference Series 1156, 1-5.
Hessami, K., Koyi, H.A., Talbot, C.J., 2001. The significance of strike slip faulting in the basement of the Zagros fold–thrust belt. Journal of Petroleum Geology 24, 5–28.
Jain, C.K., Singhal, D.C., Sharma, M.K., 2005. Metal pollution assessment of sediment and water in the river Hindon. India. Environmental Monitoring Assessment 105, 193–207.
James, G.A., Waynd, J.D., 1965. Stratigraphy nomenclature of Iranian oil Consortium Agreement area, American Association of Petroleum Geologist Bulletin 49, 2182- 2245.
Jiries, A., 2003. Vehicular contamination of dust in Amman. Jordan Environmentalist 23, 205-210.
Li, F., Huang, J., Zeng, G., Yuan, X., Li, X., Liang, J., Wang, X., Tang, X., Bai, B., 2013. Spatial risk assessment and sources identification of heavy metals in surface sediments from the Dongting Lake, Middle China. Journal of Geochemical Exploration 132, 75–83.
Lyons, W.B., Spencer, M.J., Hines, M.E., Gaudette, H.E., 1988. The trace metal geochemistry of pore water brines from two hypersaline lakes. Geochimica et Cosmochimica Acta 52, 265-274.
Lyons, W.B., Welch, S., Long, D.T., Hines, M.E., Giblin, A.M., Carey, A.E., Macumber, P.G., Lent, R.M., Herczeg, A.L., 1992. The trace-metal geochemistry of the Lake Tyrrell system brines (Victoria Australia). Chemical Geology 96, 115-132.
Mirzaei, S.Y., Zarasvandi, A., Ourang, M., 2016. Geochemical effects of Asmari oil reservoirs on the karstic water resources of Masjed-Soleyman. Advanced Applied Geology 18, 1-14.
Motiei, H., 1993. Stratigraphy of Zagros. Geological Survey of Iran, 536p.
Moyers, J.L., Ranweiler, L.E., Hopf, S.B., Korte, N.E., 1977. Evaluation of particulate traces species in southwest desert atmosphere. Environmental Science & Technology 11, 789-795.
Rastmanesh, F., Hasna, Z., Zarasvandi, A., 2019. Enrichment, origin, and health risks of heavy metals in rice farms, case study: Ahwaz and Bavi counties. Advanced Applied Geology 9, 75-84.
Rastmanesh, F., Zarasvandi, A., Moslem, F., 2015. Evaluation of heavy metal pollution in surface sediments of Karun River in Ahvaz city. Advanced Applied Geology 17, 11-22.  
Rezaei, 2016. The investigation of metallurgical potential (Na, Mg, K, Li) and heavy metals anomalies in Khuzestan Province brine springs. Internal Report, Geological Survey of Iran.
Rezaei, M., Zarasvandi, A., Azdari, A., Heidari, M., 2019. Geochemistry of heavy metals in brine springs of Khouzestan province: Tracing of pollution potential of water resources and Persian Gulf. Journal of Marine Science and Technology 18, 75-87.
Rezaei, M., Zarasvandi, A., Azdari, A., Heidari, M., 2020. Geology and hydrochemistry of brine springs in the Zagros Fold and Thrust Belt (ZFTB), Iran: A review on origin, economic potentials, and unrevealed environmental aspects. Applied Geochemistry, Under-review. 
Samanta, S., Amrutha, K., Dalai, T.K., Kumar, S., 2017. Heavy metals in the Ganga (Hooghly) river estuary sediment column: evaluation of association, geochemical cycling and anthropogenic enrichment. Environmental Earth Sciences 76, 140.
Sinex, S.A., Wright, D.A., 1988. Distribution of trace metals in the sediments and biota of Chesapeake Bay. Marine Pollution Bulletin 19, 425–431.
Song, B., Guo, G., Lei, M., Wang, Y., 2018. Assessments of contamination and human health risks of heavy metals in the road dust from a mining county in Guangxi, China. Human and Ecological Risk Assessment. An International Journal 24, 1606–1622.
Sun, Y., Zhou, Q., Xie, X., Liu, R., 2010. Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China. Journal of Hazardous Materials 174, 455-462.
Yavar Ashayeri, N., Keshavarzi, B., 2019. Geochemical characteristics, partitioning, quantitative source apportionment, and ecological and health risk of heavy metals in sediments and water: A case study in Shadegan Wetland, Iran. Marine Pollution Bulletin 149, 110495.
Yongming, H., Peixuan, D., Junji, C., Posmentier, E.S., 2006. Multivariate analysis of heavy metal contamination in urban dusts of Xi’an, Central China. The Science of the Total Environment 355, 176–186.
Zarei, M., Raeisi, R., Merkel, B.J., Kummer, N.A., 2013. Identifying sources of salinization using hydrochemical and isotopic techniques, Konarsiah, Iran. Environmental Earth Sciences 70, 587–604.
Zhang, H., Jiang, Y., Ding, M., Xie, Z., 2017. Level, source identification, and risk analysis of heavy metal in surface sediments from river-lake ecosystems in the Poyang Lake, China. Environmental Science and Pollution Research 24, 21902–21916.
Zhang, W., 2009. Heavy metal contamination in surface sediments of Yangtze River intertidal zone: An assessment from different indexes. Environmental Pollution 1, 1-11.