Geology, geochemistry and genesis of the Kosaj Fe occurrence, Takab‒Takht-e-Soleiman‒ Anguoran metalogenic zone, SW Zanjan

Authors

Department of Geology, University of Zanjan, Zanjan, Iran

Abstract

Kosaj Fe ore occurrence is located in the Takab‒Takht-e-Soleyman‒Angouran metallogenic zone. At Kosaj, iron mineralization occurs as lens-shaped bodies and layers parallel to the foliation of muscovite schist and actinolite-hornblende schist units (equal to Kahar Formation). Ore minerals are magnetite along with minor pyrite, and quartz and actinolite present as gangue mineral. The ore minerals show disseminated, laminated, banded, massive, lenticular, vein-veinlet and replacement textures. Three stages of mineralization can be distinguished at Kosaj. The first stage is recognized as stratiform and stratabound lenses, laminated and disseminated crystals of magnetite-quartz and magnetite-actinolite bands parallet to the foliation of host rocks. Stage-2 mineralization is recognized by folding of ore bands, σ microfabric, boudinage and elongation of magnetite crystals, quartz pressure shadows and surrounding of foliation around magnetite crystals, and recrystallization of quartz and magnetite crystals. Stage-3 is recognized by brecciated magnetite-quartz vein-veinlets. Actinolitization, silicification and hematitization are main hydrothermal alteration types at Kosaj. Chondrite-nonmineralized REE pattern of host rocks and the mineralized samples indicate that mineralized samples are depleted in REE. Characteristics of Kosaj occurrence are comparable with metamorphosed and deformed volcano-sedimentary type of iron deposits.

Keywords


Alderton, D.M.H., Pearce, J.A., Potts, P.J., 1980. Rare earth element mobility during granite alteration: Evidence from Southwest England. Earth Planet Scientific Letters 49, 149-165.
Asadi, H.H., Voncken, J.H.L., Kühnel, R.A. and Hale, M., 1999. Invisible gold at Zarshuran, Iran. Economic Geology 94, 1367-1374.
Asadi, H.H., Voncken, J.H.L., Kühnel, R.A., Hale, M., 2000. Petrography, mineralogy and geochemistry of the Zarshuran Carlin-like gold deposit, northwest Iran. Mineralium Deposita 5, 656-671.
Ashley, P.M., Lottermoser, B.G., Westaway, J.M., 1998. Iron-formation and epigenetic ironstones in the Palaeoproterozoic Willyama Supergroup, Olary Domain, South Australia. Mineralogy and Petrology 6, 187-218.
Babakhani, A.R., Ghalamghash, J., 1996. Geological map of Takht-e-Soleyman, scale 1:100000. Geological Survey of Iran.
Barker, A.J., 1991. An introduction to metamorphic textures and microstructures. Oxford University press, 209 pp.
Barragan, R., Geist, D., Hall, M., Larsen, P., Kurz, M., 1998. Subduction controls on the compositions of lavas from the Ecuadorian Andes. Earth and Planetary Science Letters 154, 153-166.
Bienvenu, P., 1990. MORB alteration: Rare earth element/non-rare hydromagmaphile element fractionation. Chemical Geology 82, 1-14.
Boni, M., Gilg, H.A., Balassone, G., Schneider, J., Allen, C.R., Moore, F., 2007. Hypogene Zn carbonate ores in the Angourandeposit, NW Iran. Mineralium Deposita 42, 799-820.
Boynton, W.V., 1984. Cosmochemistry of the earth element: meteorite studies. In: Henderson, P., (Ed.): Rare Earth Element geochemistry. Elsevier, Amsterdam, pp: 63-114.
Brunsmann, A., Franz, G., Erzinger, J., 2001. REE mobilization during small-scale high-pressure fluid-rock interaction and zoisite/fluid partitioning of La to Eu. Geochemica et Cosmochimica Acta 65(4), 559-570.
Ciftci, D., Unlu, T., Sayili, S.A., 1996. Discussion on the origin of Otlukiliseiron deposit Gurun- Sivas. Mineral Resource Exploration Bulletin 118, 25-50.
Corona-Esquivel, R., Ortega-Gutiérrez, F., Reyes-Salas., M., Lozano-Santacruz, R., Miranda-Gasca, M.A., 2000. Mineralogical study of the La Hueca Cretaceous ironmanganese deposit, Michoacan, Southwestern Mexico. Revista Mexicana de Ciencias Geológicas 17(2), 143-153.
Craige, J.R., Vaughan, D.L., 1994. Ore Microscopy and Ore Petrography.  2nd ed., New York, John Wiley and Sons, 434 p.
Daliran, F., 2008. The carbonate rock-hosted epithermal gold deposit of Agdarreh, Takab geothermal field, NW Iran, hydrothermal alteration and mineralization. Mineralium Deposita 4, 383-404.
Daliran, F., Hofstra, A.H., Walther, J., Stüben, D., 2002. Aghdarreh and Zarshuran SRHDG deposits, Takab region, NW Iran. GSA Annual Meeting, Abstract with Programs, Session 63-8.
Daliran, F., Pride, K., Walther, W., Berner, Z.A., Bakker, R.J., 2013. The Angouran Zn (Pb) deposit, NW Iran: evidence for a two stage, hypogene zinc sulfide–zinc carbonate mineralization. Ore Geology Reviews 53, 373-402.
Daliran, F., Walther, J., Stüben, D., 1999. Sediment-hosted disseminated gold mineralization in the North Takab geothermal field, NW-Iran. In: Stanley, C.J. et al. (Eds.): Mineral Deposits: Processes to Processing. Proceed. 5th bienn. SGA Meeting and 10th Quadr. IAGOD Meeting, pp. 837-840.
Dixon, J.E., Leist, L., Langmuir, C., Schilling, J.G., 2002. Recycled dehydrated lithosphere observed in plume-influenced mid-ocean-ridge basalt. Nature 420, 385-389.
Dokuz, A., Tanyolu, E., Genc, S., 2005. A mantle and a lower crust derived bimodal suite in the Yusufeli Artvin area, NE Turkey: Trace element and REE evidence for Subduction-related rift origin of Early Jurasic Demirkent intrusive complex. International Journal of Earth Sciences (Geologische Rundsch) 95(3), 370-394.
Feridooni, Z., 2017. Geology, mineralogy and geochemistry of Halab 1 Fe mineralization, southwest Zanjan. Unpublished M.Sc. Thesis, University of Zanjan, Iran, (in Persian with English abstract).
Fitton, J.G., James, D., Leeman, W.P., 1991. Basic magmatism associated with Late Cenozoic extension in the Western United States: compositional variations in space and time. Journal of Geophysical Research 96, 13693-13712.
Giere, R., Williams, C.T., 1992. REE-bearing minerals in a Ti-rich vein from the Adamello contact aureole (Italy). Contributions to Mineralogy and Petrology 112(1), 83-100.
Gilg, H.A., Boni, M., Balassone, G., Allen, C.R., Banks, D., Moore, F., 2006. Marble-hosted sulphide ores in the Angouran Zn-(Pb-Ag) deposit, NW Iran: interaction of sedimentary brines with a metamorphic core complex. Mineralium Deposita 4, 1-16.
Gramaccioli, C.M., Diella, V., Demartin, F., 1999. The role of fluoride complexes in REE geochemistry and the importance of 4f electrons: some complexes in minerals. European Journal of Mineralogy 11(6), 983-992.
Heidari, M., 2013. Geology, dating and genesis of the Touzlar, Aabshah and Qozalbolaq Au occurrences, Qorveh-Takab area. Unpublished PhD Thesis, Tarbiat Modares University, Tehran, Iran, 459 pp. (In Persian with English abstract).
Heidari, M., Daliran, F., Paquette, J.L., Gasquet, D., 2015a. Geology, timing, and genesis of the high sulfidation Au (Cu) deposit of Touzlar, NW Iran. Ore Geology Reviews 65, 460-486.
Heidari, M., Ghaderi, M., Kouhestani, H., 2015b, Touzlar epithermal Au-Ag (Cu) deposit, subvolcanic intrusion-related of intra-arc extentional setting, northwest Mahneshan, Iran. Scientific Quarterly Journal, Geosciences 24(95), 329-348. (In Persian with English abstract).
Humphris, S.E., 1984. The mobility of the rare earth elements in the crust. In: Henderson, P., (Ed.): Rare earth element geochemistry. Elsevier, Amsterdam, pp: 317-342.
Karami, F., 2018. Geology, geochemistry and genesis of Halab Zn–Pb (Ag) deposit (SW Zanjan). Unpublished M.Sc. Thesis, University of Zanjan, Zanjan, Iran, 122 pp. (In Persian with English abstract).
Kato, Y., Ohta, I., Tsumematsu, T., Watanabe. Y., I., Maruyama, S., Imai, N., 1998. Rare earth element variations in mid-Archean banded iron formations: Implications for the chemistry of ocean and continent and tectonics. Geochimica et Cosmochimca Acta 62, 3475-3497.
Kikawada, Y., Ossaka. T., Oi, T., Honda, T., 2001. Experimental studies on the mobility of lanthanides accompanying alteration of andesite by acidic hot spring water. Chemical Geology 176(1-4), 137-149.
Kontny, A., Engelmann, R., Grimmer, J.C., Greiling, R.O., Hirt, A., 2012. Magnetic fabric development in a highly anisotropic magnetite-bearing ductile shear zone (Seve Nappe Complex, Scandinavian Caledonides. International Journal of Earth Sciences (Geol Rundsch) 101, 671-692.
Lanza, R., Pioli, L., ORT, M., Rosi, M., 2008. Magnetic fabric, welding texture and strain fabric in the Nuraxi Tuff. Sardinia, Italy. Bull Volcano 70, 1123-1137.
Lottermoser, B.G., 1992. Rare earth elements and hydrothermal ore formation processes. Ore Geology Reviews 7(1), 25-41.
McDonough, W.F., Sun, S.S., 1995. Composition of the Earth. Chemical Geology 120, 223-253.
Mehrabi, B., Yardley, B.W.D., Cam, J.R., 1999. Sediment-hosted disseminated gold mineralization at Zarshuran, NW Iran. Mineralium Deposita 34, 673-696.
Mohammadi Niaei, R., 2014. Genesis and economic geology of Ay Qalasi Pb-Zn deposit with special view on mineralization of precious metals. Unpublished Ph.D. Thesis, Science and Research Branch, Islamic Azad University, Iran, 210 pp. (in Persian with English abstract)
Mohammadi Niaei, R., Daliran, F., Nezafati, N., Ghorbani, M., Sheikh Zakariaei, J., Kouhestani, H., 2015. The Ay Qalasi deposit: An epithermal Pb–Zn (Ag) mineralization in the Urumieh-Dokhtar Volcanic Belt ofnorthwestern Iran. Neues Jahrbuch für Mineralogie Abhandlungen 192 (3), 263-274.
Mohammadi, Z., Ebrahimi, M., Kouhestani, H., 2014. The Goorgoor Fe occurrence, NE of Takab: A metamorphosed volcano-sedimentary mineralization in the Sanandaj–Sirjan zone. Advanced Applied Geology 4(13), 20-32. (In Persian with English abstract).
Murphy, J.B., Hynes, A.J., 1986. Contrasting secondary mobility of Ti, P, Zr, Nb and Y in two metabasaltic suites in the Appalachians. Canadian Journal of Earth Sciences 23, 1138-1144.
Nafisi, R., Kouhestani, H., Mokhtari, M.A.A., Sadeghi, M., 2019. Geochemistry and tectonomagmatic setting of protolite rocks of meta-volcanics in the Halab metamorphic complex (SW Dandy, Zanjan Province). Journal of Economic Geology 11(2), 211–235. (In Persian with extended English abstract)
Passchier. C.W., Trouw. R.A.J., 1997. Micro-tectonics. Springer-Verlag New York, Berlin Heidelberg Editions, 289 p.
Pourmohamad, F., Kouhestani, H., Azimzadeh, A.M., Nabatian, Gh., Mokhtari, M.A.A., 2019. Mianaj iron occurrence, southwest of Zanjan: Metamorphosed and deformed volcano-sedimentary type of mineralization in Sanandaj–Sirjan zone. Scientific Quarterly Journal, Geosciences 28(111), 161–174 (In Persian with English abstract).
Quade, H., Carlos, A., Rosiere, H.S., Heinz-Gunter, B., Janson, E.M., 2001. Microstructures, textures and deformation in hematite. Jurnal of Structural Gelogy 23, 1429-1440.
Rolland, Y., Cox, S., Boullier, A.M., Pennacchioni, G., Mancktelow, N., 2003. Rare earth and trace element mobility in mid-crustal shear zones: insights from the Mont Blanc Massif (Western Alps). Earth Planet Scientific Letters 214, 203-219.
Rostami, H., 2014. Kosaj Fe exploration report. Ministry of Industry, Mine and Trade, Zanjan Province, Zanjan, Iran, 139 pp. (In Persian).
Roy, S., Venkatesh. A.S., 2009. Mineralogy and geochemistry of banded iron formation and iron ores from eastern India with implications on their genesis. Science 118, 619-641.
Saal, A.E., Kurz, M.D., Hart, S.R., Blusztajn, J.S., Blichert-Toft, J., Liang, Y., Geist, D.J., 2007. The role of lithospheric gabbros on the composition of Galapagos lavas. Earth Planet Scientific Letters 257, 391-406.
Shirkhani, M., 2007. Mineralogy, geochemistry and genesis of Ay Qalasi Pb-Zn deposit, SE Takab. Unpublished M.Sc. Thesis, Tarbiat Modares University, Iran, 143 pp. (in Persian with English abstract).
Smirnov, V.M., Ginzburg, A.I., Grigoriev, V.M., Yakovlev, G.F., 1983. Studies of mineral deposits. Mir Publishers, Moscow, 288 p.
Stöcklin, J., 1968. Structural history and tectonics of Iran: A review. American Association of Petroleum Geologists 52, 1229-1258.
Thompson, R.N., 1982. Magmatism of the British Tertiary province. Scottish Journal of Geology 18, 49-107.
Tofighi, F., Mokhtari, M.A.A., Izadyar, J., Kouhestani, H., 2019. Geology and genesis of Halab 2 Fe occurrence in Takab–Takht-e-Soleiman–Anguoran metallogenic zone. Advanced Applied Geology 8(27), 44-59 (In Persian with English abstract).
Wang, Q., Wyman, D.A., Xu, J.F, Zhao, Z.H., Jian, P., Xiong, X.L., Bao, Z.W., LI, C.F., Bai, Z.H., 2006. Petrogenesis of Cretaceous adakitic and shoshonitic igneous rocks in the Luzong area, Anhui province (Eastern China): Implications for geodynamics and Cu-Au mineralization. Lithos 89, 1-26.
Whitford, D.J., Korsch M.J., Porritt P.M., Craven, S.J., 1988. Rare-earth element mobility around the volcanogenic polymetallic massive sulfide deposit at Que River, Tasmania, Australia. Chemical Geology 68, 105-119.
Whitney, D.L., Evans, B.W., 2010. Abbreviations for names of rock-forming minerals. American Mineralogist 95, 185-187.
Wilson, M., 1989. Igneous Petrogenesis-A global tectonicn approach. Unwin Hyman London, 466 p.
Wood, S.A., 1990a. The aqueous geochemistry of the rare earth elements and Yttrium. 1: Review of available low-temperature data for inorganic complexes and the inorganic REE speciation of natural waters. Chemical Geology 82, 159-186.
Wood, S.A., 1990b. The aqueous geochemistry of the rare earth elements and Yttrium. 2: Theoretical predictions of speciation in hydrothermal solutions to 350 ºC at station water vapor pressure. Chemical Geology 88(1-2), 99-125.
Yardley, B.W.D., Mackenzie, W.S., Guilford. C., 1990. Atlas of metamorphic rocks and their textures. Longman Scientific and technical 120 p.
Zhuang, L., Song, Y., Liu, Y., Fard, M., Hou, Z., 2019. Major and trace elements and sulfur isotopes in two stages of sphalerite from the world-class Angouran Zn–Pb deposit, Iran: Implications for mineralization conditions and type. Ore Geology Reviews 109, 184-200.