“Kutnohorite”: Mineralogy database and alteration types in the Koushk deposit (Bafq, Central Iran)

Authors

Department of Earth Sciences, Shiraz University, Shiraz, Iran

Abstract

The Koushk Zn-Pb shale-hosted massive sulfide deposit is located in the north east of Bafq area within the sequence of lithostratigraphical Rizu unit in the Central Iran (Posht-Badam block). During this study, for the first time in Iran, unknown pink vein minerals are contemporaneous with quartz, located in most of the north and south Pahno stratigraphic units has been introduced as Kutnohorite mineral in the Koushk deposit. Kutnohorite is a type of manganese carbonate with the chemical formula "CaMn2+(CO3)2", belong to the dolomite group. Sampling and geochemical analyses of volcanic-sedimentary host rocks (rhyolite, tuff, shale and dolomite) indicate that high amounts of chlorite, sericite, clinochlore, and euhedral pyrite minerals are found with kutnohorite-quartz veins and associated with galena and sphalerite ores at north Pahno section of the Koushk deposit. According to determining the types of alteration associated with kutnohorite-bearing zone using Ishikawa and chlorite-carbonate-pyrite (CCPI) indices showed that this mineral is an indicator and exploratory key in the Zn-Pb shale-hosted massive sulfide deposits such as the Koushk ore deposit.

Keywords


Alavi, M., 1991. Sedimentary and structural characteristics of the Paleo-Tethys remnants in northeastern Iran. Geological Society of America Bulletin 103(8), 983-992.
Alavi, M., 1991. Tectonic map of the Middle East: Tehran, Geological Survey of Iran scale1: 5,000,000.
Asadi, S., 2013. Geochemistry of selected productive and barren intrusions in Shahr Babak copper complex, Urumiyeh–Dokhtar volcano–magmatic belt. Ph.D. thesis, Shiraz, Iran, Shiraz University, 222 pp.
Asadi, S., Rajabzadeh, M.A. 2014. Geochemistry, paragenesis, and wall-rock alteration of the Qatruyeh iron deposits, southwest of Iran: Implications for a hydrothermal-metasomatic genetic model. Journal of Geological Research 2014, 1-24.
Forster, H., Jafarzadeh, A., 1994. The Bafq mining district in central Iran; a highly mineralized Infracambrian volcanic field. Economic Geology 89, 1697-1721.
Frondel, C., Bauer, L., H., 1955. Kutnahorite: A manganese dolomite, CaMn(CO3)2, American Mineralogist 40, 748-760.
Gabrielson, O., Sundius, N., 1966. Calcian kutnahorite from Lingban. Arkansas Mineralogy and Geology 4, 287-289.
Ghorbani, M., 2002. The Economic Geology of Iran (Mineral Deposits and Natural Resources), Springer Dordrecht Heidelberg New York London.
Haghipour, A., 1977. Geological map of the Biabanak-Bafq, area, 1: 500000, Geological Survey of Iran, Tehran.
Ishikawa, Y., Sawaguchi, T., Iwaya, S., Horiuchi, M., 1976. Delineation of prospecting targets for Kuroko deposits based on modes of volcanism of underlying dacite and alteration haloes. Mining Geology 26, 105-117.
Large, R.R., 2001. Lithogeochemical Halos: VHMS and SEDEX, Centre for Ore Deposit Research (CODES), University of Tasmania.
Large, R.R., Allen, R.L., Blake, M.D., Herrmann, W., 2001. Hydrothermal Alteration and Volatile Element Halos for the Rosebery K Lens Volcanic-Hosted Massive Sulfide Deposit, Western Tasmania. Economic Geology 96, 1055-1072.
Large, R.R., Bull, S.W., Winefield, P.R., 2001. Carbon and oxygen isotope halo in carbonates related to the McArthur River (HYC) Zn-Pb-Ag deposit, north Australia: Implications for sedimentation, ore genesis, and mineral exploration. Economic Geology 96(7), 1567-1593.
Large, R.R., Gemmell, J.B., Paulick, H., Huston, D.L., 2001. The alteration box plot: A simple approach to understanding the relationship between alteration mineralogy and lithogeochemistry associated with volcanic-hosted massive sulfde deposits. Economic Geology 96(5), 957-971.
NISCO, 1980. Report on results of search and evaluation works at magnetic anomalies of the Bafq iron ore region during 1976-1979, 260p.
Polgari, M., 2001. Contribution of volcanic material, a new aspect of the genesis of the black shale-hosted Jurassic Mn-carbonate ore formation, Úrkút Basin, Hungary. Acta Geologica Hungarica 44(4), 419-438
Polgari, M., Bajnóczi, B., KovácsKis, V., Götze, J., Dobosi, G., Tóth, M., Vigh, T., 2007. Mineralogical and cathodoluminescence characteristics of Ca-rich kutnohorite from the Úrkút Mn-carbonate mineralization, Hungary. Mineralogical Magazine 71, 493-508.
Ramezani, J., Tucker, R. D., 2003. The Saghand region, central Iran: U-Pb geochronology, petrogenesis and implications for Gondwana tectonics. American Journal of Science 303(7), 622-665.
Richard, P., Jiří, S., Vladimir, S., 2019. Ag-Pb-Sb Sulfosalts and Se-rich Mineralization of Anthony of Padua Mine near Poličany—Model Example of the Mineralization of Silver Lodes in the Historic Kutná Hora Ag-Pb Ore District, Czech Republic. Minerals 9, 430.
Vaziri, H., Majidifard, M.R., Lafamme, M., 2018. Diverse Assemblage of Ediacaran fossils from Central Iran. Nature 7, 1-7.
Zolfaghari, A., 2019. The potential of Precious Metals and Rare Earth Elements in Pb and Zn Kushk mine -Yazd, Central Iran. M.Sc Thesis, Department of Earth Sciences at Shiraz University, Shiraz.