The Hydrogeochemistry of Groundwater in Zirab Coal Mine

Authors

Department of Geology, Faculty of Earth Sciences, Shahid Beheshti University, Tehran, Iran

Abstract

      Groundwater samples from five springs and one reservoir (monthly) and four drinking water wells (two times in one year) have been collected from 2007 to 2008 year. The geochemical evolution of groundwater in the study area has been affected by carbonate dissolution. The increase of chloride concentrations in the wet seasons in Tunnel Dah Dastgah, Kanich Kala, and Tunnel Pish springs could be attributed to the recharge from the mine galleries and coal layers. The anomalous increase in sodium and chloride concentrations versus to total dissolved solids in Googerdi Maadan and Tunnel Dah Dastgah springs indicate the recharge from coal layers in Shemshak formation. The mixing of infiltrated water from the coal layers with groundwater has been leaded to the increase of incongruent dissolution in the water / rock system. The cluster analysis of the hydrochemical data indicates that the drinking water wells are not affected by the coal layers. The sulfur smell of Maadan spring is a result of sulfate reduction in the aquifer.
 

Keywords


شرکت ذغال سنگ البرز مرکزی، 1365، مطالعات زمین شناسی و آبشناسی مناطق ذغال سنگی آلاشت، مجتمع ذغال سنگ البرز مرکزی.
Alley, W. M., 1993, Regional Ground-Water Quality, Van Nostrand Reinhold, New York.
Ayenew, T., Fikre. S.,  Wisotzky. F., Demlie. M., Wohnlich. S. 2009, Hierarchical cluster analysis of hydrochemical data as a tool for assessing the evolution and dynamics of groundwater across the Ethiopian rift, International Journal of Physical Sciences, Vol:4, No:2, p:76-90.
Bates. B. L., McIntosh. J.C., Lohse. K.A., Brooks. P.D. 2011, Influence of groundwater flowpaths, residence times and nutrients on the extent of microbial methanogenesis in coal beds: Powder River Basin, USA, Chemical Geology, Vol:284, No:1-2, p:45-61.
Belkhiri. L., Boudoukha. A., Mouni. L., 2011, A multivariate statistical analysis of groundwater chemistry data, Int. J. Environ. Res., Vol:5, No:2, p:537-544.
Currell. M.J., Cartwright. I., 2011, Major-ion chemistry, δ13C and 87Sr/86Sr as indicators of hydrochemical evolution and sources of salinity in groundwater in the Yuncheng Basin, China, Hydrogeology Journal, Vol:19, p:835-850.
Kim. J.H., Kim. R.H., Lee. J.H., Cheong. T.J., Yum. B.W., Chang. H.W., 2005, Multivariate statistical analysis to identify the major factors governing groundwater quality in the coastal area of Kimje, South Korea, Hydrological Processes, Vol:19, No:6, p:1261-1276.
Kinnon. E.C.P., Golding. S.D., Boreham. C.J., Baublys. K.A., Esterle. J.S., 2010, Stable isotope and water quality analysis of coal bed methane production waters and gases from the Bowen Basin, Australia, International Journal of Coal Geology, Vol:82, No:3-4, p:219-231.
Langmuir. D., 1997, Aqueous Environmental Geochemistry, Prentice Hall, New Jersey.
Liu. S.Q., Li.  J.G., Mei. M., Dong. D.L., 2007, Groundwater pollution from underground coal gasification, Journal of China University of Mining and Technology, Vol:17, No:4, p:467-472.
Meng. S.X., Maynard. J.B., 2001, Use of statistical analysis to formulate conceptual models of geochemical behavior: water chemical data from Butucatu aquifer in Sao Paulo State, Brazil, Journal of Hydrology, Vol:250, p:78-97.
Nwankwoala. H.O., Udom. G.J., 2011, Hydrochemical facies and ionic ratios of groundwater in Port  arcourt, southern Nigeria, Research Journal of Chemical Sciences, Vol:1, No:3, p:87-101.
47
 
Parkhurst. D.L., Appelo. C.A.J., 1999, User’s guide to PHREEQC (Version2) - A computer program forspeciation, batch-reaction, one-dimensional transport, and inversegeochemical calculations, U.S.Geological Survey Water-ResourcesInvestigations Report 99-4259, 310.
Qiao. X., Li. G., Li. M., Zhou. J., Du. J., Du. C., Sun. Z., 2010, Influence of coal mining on regional karst groundwater system: a case study in West Mountain area of Taiyuan City, northern China, Environ Earth Sci., DOI 10.1007/s12665-010-0586-3.
Peiyue. L., Hui. Q., Jianhua. W.U., 2011, Hydrochemical characteristics and evolution laws of drinking groundwater in Pengyang County, Ningxia, northwest China, E-Journal of Chemistry, Vol:8, No:2, p:565-575.
Reghunath. R., Murthy. T.R.S., Raghavan. B.R., 2002, The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India, Water Research, VCol:36, No:10, p:2437-2442.
Suk. H.J., Lee. K.K., 1999, Characterization of a ground water hydrochemical system through multivariate analysis: clustering into ground water zones, Ground Water, Vol:37, No:3, p:358-366.
Van Voast. W.A., 2003, Geochemical signature of formation waters associated with coalbed methane, AAPG Bulletin, Vol:87, No:4, p:667-676.